Review of low-temperature electrolyte of lithium-ion batteries for near space vehicle
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摘要:
临近空间的低温环境对临近飞行器的电源系统提出了更高的要求。空间用锂离子电池(LIBs)作为空间电源系统的主要组成部分，在极端环境中的正常运行仍然面临着极高的技术壁垒。电解液，包括电解液本体相及固态电解质界面(SEI)膜，对锂离子电池在低温下的稳定运行十分关键。因此，开发先进的低温电解液对于锂离子电池在极端寒冷环境中稳定运行极其重要。从锂离子电池电解液角度出发，针对限制锂离子电池低温性能差的原因，综述了改善锂离子电池低温电解液的相关策略，对面向临近空间飞行器的锂离子电池低温电解液设计现状进行了分析。
Abstract:Higher demands have been placed on the power system of near-space missions due to the low-temperature environment. Lithium-ion batteries (LIBs), the primary power source for space systems, have significant technical obstacles to normal operation in harsh environments due to their rapid capacity deterioration and eventual battery failure at below-freezing temperatures. E For LIBs to function at low temperatures, electrolyte—including bulk electrolyte and solid electrolyte interface (SEI) film—is essential. Therefore, the development of advanced electrolyte for low-temperature conditions is important for the operation of LIBs in extremely cold environments. The design status of the low-temperature electrolyte of LIBs for near-space vehicles was evaluated, along with a summary of pertinent strategies to improve the LIBs of electrolyte for low-temperature conditions, with the goal of identifying the factors limiting the low-temperature performance of LIBs. This work provides a feasible strategy for the development of Energy storage equipment in near-space vehicles.
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图 8 Li+从电解液到石墨负极的扩散过程示意图
Figure 8. Schematically illustration of Li+ diffusion process from electrolyte to electrode
图 10 不同电解液结构示意图
Figure 10. Illustrations of the solution structures different electrolytes
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