| Citation: | YANG X Y，MA W B，XIE S. Influence of slight over-discharge on aging behavior of lithium-ion batteries in high-temperature environments[J]. Journal of Beijing University of Aeronautics and Astronautics，2024，50（12）：3903-3911 （in Chinese） doi: 10.13700/j.bh.1001-5965.2023.0634
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The extreme high-temperature weather that has occurred worldwide in recent years has significantly increased the probability of lithium-ion batteries operating in high-temperature environments. The battery consistency difference caused by the operating environment and system management makes the battery prone to slight over-discharge. The coupling between high-temperature environment and over-discharge phenomenon significantly increases the risk of battery safety accidents. In order to study the influence of high-temperature environment and slight over-discharge coupling on the aging behavior of lithium-ion batteries, this paper carried out a slight over-discharge experiment on ternary lithium-ion batteries at 60 °C (high temperature) and 25 °C (normal temperature). The results show that the battery capacity attenuation rates after 100 cycles of slight over-discharge at 60 °C and 25 °C are 28.46% and 2.54%, respectively. Compared with that in normal temperature environments, slight over-discharge in high-temperature environments significantly increases the battery capacity attenuation. The electrochemical analysis of the battery shows that high temperatures limit the lithium deintercalation reaction inside the battery, increase the loss of active lithium, and degrade the kinetic performance. Battery disassembly photos, scanning electron microscopy, and elemental analysis results prove that slightly over-discharged batteries in high-temperature environments are severely deformed, and more sediments are produced by battery side reactions. Therefore, the coupling of a high-temperature environment and slight over-discharge will aggravate the damage of the cathode structure and internal side reactions, leading to a decline in battery performance. The research results can provide an experimental reference and theoretical basis for the development of lithium-ion battery materials and the safe operation of electric vehicles.
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